Serveur d'exploration sur le thulium

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Thortveitite-type Tm2Si2O7

Identifieur interne : 000241 ( Main/Exploration ); précédent : 000240; suivant : 000242

Thortveitite-type Tm2Si2O7

Auteurs : Volker Kahlenberg [Autriche] ; Paul Aichholzer [Autriche]

Source :

RBID : PMC:4120532

Abstract

Single crystals of dithulium disilicate, Tm2Si2O7, were obtained in flux synthesis experiments in the system SiO2–Tm2O3–LiF at ambient pressure. The compound belongs to the group of sorosilicates, i.e. it is based on [Si2O7]-units and crystallizes in the thortveitite (Sc2Si2O7) structure type. The Tm3+ cation (site symmetry .2.) occupies a distorted octa­hedral site, with Tm—O bond lengths in the range 2.217 (4)–2.289 (4) Å. Each of the octa­hedra shares three of its edges with adjacent [TmO6] groups, resulting in the formation of layers parallel to (001). The individual [SiO4] tetra­hedra are more regular, i.e. the differences between the bond lengths between Si and the bridging and non-bridging O atoms are not very pronounced. The layers containing the octa­hedra and the sheets containing the [Si2O7] groups (point group symmetry 2/m) form an alternating sequence. Linkage is provided by sharing common oxygen vertices.


Url:
DOI: 10.1107/S1600536814013142
PubMed: 25161507
PubMed Central: 4120532


Affiliations:


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Le document en format XML

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Si
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O
<sub>7</sub>
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<nlm:aff id="a">University of Innsbruck, Institute of Mineralogy & Petrography, Innrain 52, A-6020 Innsbruck,
<country>Austria</country>
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<sub>2</sub>
Si
<sub>2</sub>
O
<sub>7</sub>
</title>
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<name sortKey="Kahlenberg, Volker" sort="Kahlenberg, Volker" uniqKey="Kahlenberg V" first="Volker" last="Kahlenberg">Volker Kahlenberg</name>
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<country>Austria</country>
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<title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
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<p>Single crystals of dithulium disilicate, Tm
<sub>2</sub>
Si
<sub>2</sub>
O
<sub>7</sub>
, were obtained in flux synthesis experiments in the system SiO
<sub>2</sub>
–Tm
<sub>2</sub>
O
<sub>3</sub>
–LiF at ambient pressure. The compound belongs to the group of sorosilicates,
<italic>i.e.</italic>
it is based on [Si
<sub>2</sub>
O
<sub>7</sub>
]-units and crystallizes in the thortveitite (Sc
<sub>2</sub>
Si
<sub>2</sub>
O
<sub>7</sub>
) structure type. The Tm
<sup>3+</sup>
cation (site symmetry .2.) occupies a distorted octa­hedral site, with Tm—O bond lengths in the range 2.217 (4)–2.289 (4) Å. Each of the octa­hedra shares three of its edges with adjacent [TmO
<sub>6</sub>
] groups, resulting in the formation of layers parallel to (001). The individual [SiO
<sub>4</sub>
] tetra­hedra are more regular,
<italic>i.e.</italic>
the differences between the bond lengths between Si and the bridging and non-bridging O atoms are not very pronounced. The layers containing the octa­hedra and the sheets containing the [Si
<sub>2</sub>
O
<sub>7</sub>
] groups (point group symmetry 2/
<italic>m</italic>
) form an alternating sequence. Linkage is provided by sharing common oxygen vertices.</p>
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